1474032-69-3Relevant academic research and scientific papers
Gold-catalyzed intermolecular oxidation of terminal alkynes: Simple and efficient synthesis of α-mesyloxy ketones
Xie, Longyong,Liang, Zhiwu,Yan, Dong,He, Weimin,Xiang, Jiannan
, p. 1809 - 1812 (2013)
A variety of terminal alkynes were efficiently converted into the corresponding α-mesyloxy ketones through gold-catalyzed intermolecular oxidation in the presence of 3,5-dichloropyridine N-oxide as the oxidant. The reaction is proposed to proceed via α-oxo gold carbene intermolecular O-H insertion. Georg Thieme Verlag Stuttgart · New York.
