1474045-90-3Relevant academic research and scientific papers
A mild, facile, one-pot synthesis of zinc azido porphyrins as substrates for use in click chemistry
Bryden, Francesca,Boyle, Ross W.
supporting information, p. 1978 - 1982 (2013/09/24)
The conversion of porphyrins bearing primary amines into zinc-protected azido porphyrins utilising a diazo-transfer reagent is reported. This method allows the mild, facile, and one-pot synthesis of zinc azido porphyrins bearing a range of meso functionalities, producing the required porphyrin in high yield. Reactivity of the azide functionality is demonstrated by subsequent model click reactions to produce triazole derivatives. Georg Thieme Verlag Stuttgart New York.
