147424-62-2

Basic information

• Product Name: Naphthalene, 1-(2,6-dimethylphenyl)-
• CAS NO: 147424-62-2
• Molecular Formula: C18H16
• Molecular Weight: 232.325
• Mol File: 147424-62-2.mol
• Article Data: 53

Chemical Properties

• Melting Point: 67-68 °C
• Boiling Point: 334.3±27.0 °C(Predicted)
• Density: 1.049±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Naphthalene, 1-(2,6-dimethylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Naphthalene, 1-(2,6-dimethylphenyl)-(147424-62-2)
• EPA Substance Registry System: Naphthalene, 1-(2,6-dimethylphenyl)-(147424-62-2)

Safety Data

• Hazardous Substances Data: 147424-62-2(Hazardous Substances Data)

Upstream product

• 90-11-9 1-Bromonaphthalene 
• 100379-00-8 2,6-dimethylbenzene boronic acid 
• 576-22-7 2-Bromo-m-xylene 
• 13922-41-3 1-Naphthylboronic acid 
• 86-57-7 1-Nitronaphthalene 
• 1144-13-4 naphthalen-1-yl N,N-dimethylsulfamate 
• 608-28-6 2,6-dimethyliodobenzene 
• 22871-77-8 5,5-dimethyl-2-(naphthalen-1-yl)-1,3,2-dioxaborinane 
• 90-13-1 1-Chloronaphthalene 
• 21450-64-6 (2,6-dimethylphenyl)magnesium bromide 
• 703-55-9 1-naphthylmagnesiumbromide 
• 6781-98-2 2,6-dimethyl-1-chlorobenzene 
• 6301-54-8 2-(naphthalen-1-yl)propan-2-ol 
• 63509-96-6 2,6-xylyllithium 

Downstream Products

• 662143-38-6 1,3-bis(mercaptomethyl)-2-(1-naphthyl)benzene 
• 662143-35-3 1,3-bis(bromomethyl)-2-(1-naphthyl)benzene 

Relevant articles and documents

General and efficient methodology for the Suzuki-Miyaura reaction in technical grade 2-propanol

The reaction profile of a series of palladium-based catalysts was examined in the Suzuki-Miyaura reaction using technical grade 2-propanol as solvent and potassium t-butoxide as base. The results generally show high activity. The method allows for the coupling of electron-rich aryl chlorides with sterically hindered aryl boronic acids to produce tri-ortho-substituted biaryls in high yields using very mild conditions and short reaction times.

Site-selective covalent functionalization at interior carbon atoms and on the rim of circumtrindene, aC36H12 open geodesic polyarene

Circumtrindene (6, C, one of the largest open geodesic polyarenes ever reported, exhibits fullerene-like reactivity at its interior carbon atoms, whereas its edge carbons react like those of planar polycyclic aromatic hydrocarbons (PAHs). The Bingel-Hirsc

Palladium(II) Complexes of a Neutral CCC-Tris(N-heterocyclic carbene) Pincer Ligand: Synthesis and Catalytic Applications

Treatment of tris-azolium precursor 1 with palladium acetate under thermal conditions provided a CCC-pincer palladium(II) complex (2) bearing three NHCs (one imidazolylidene and two triazolylidenes) and one iodide ligand. Further treatment of complex 2 with an excess of AgSbF6 generates tris(carbene) dicationic palladium complex 3 in which the iodine ligands are exchanged with SbF6 anions and the metal center is stabilized by one acetonitrile ligand. Complexes 2 and 3 were tested in several cross coupling reactions showing high conversions under low catalyst loadings and mild reaction conditions. Additionally, complexes 2 and 3 performed well in the hydrosilylation of terminal alkynes with good selectivity toward the E-isomer.

A substituted tricyclohexylphosphane with “conformational lock”

A substituted tricyclohexylphosphane with “conformational lock”, tri(4-trans-(tert-butyl)cyclohexyl)phosphane L, has been designed and synthesized. The ligand has shown similar steric bulkiness and conformations to tricyclohexylphosphane at solid state. The comparable or slightly better performance of ligand L compared to PCy3 in Suzuki-Miyaura coupling has demonstrated the similar steric properties of two ligands in reaction and the effectiveness of the chair conformer of the cyclohexyl rings. The ineffectiveness of both L and PCy3 in palladium-catalyzed aminations has also manifested the weakness of such ligands and a sterically more bulky ligand is needed in order to develop a more efficient amination.