14753-05-0Relevant articles and documents
Studies on Sulphochlorination of Paraffins. IX. Regularities of the Sulphochlorination of Branched-chain Paraffins
Estel, D.,Mateew, K.,Pritzkow, W.,Schmidt-Renner, W.
, p. 262 - 268 (2007/10/02)
In the cases of 2-methylbutane and 2-methylpentane the formation of tertiary sulphochlorides in the sulphochlorination of the parent hydrocarbons could be established by means of 13C-n.m.r.-spectroscopy.The relative rates of the various C-H-bonds in 2-methylbutane, 2-methylpentane and 3-methylpentane in the sulphochlorination reaction were determined.The relative rates of the tertiary C-H-bonds in the sulphochlorination were considerably lower than the corresponding values for the chlorination of the branched-chain paraffins.
Alkylation of alkyl, cycloalkyl and aralkyl halides
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, (2008/06/13)
Alkyl, cycloalkyl or aralkyl halides may be alkylated by treatment with an olefin in the presence of a catalyst comprising a free-radical generating compound such as an organic peroxide and also in the presence of a promoter comprising hydrogen chloride, said alkylation reaction being effected at temperatures at least as high as the decomposition temperature of the free-radical generating compound, to prepare alkylated halide-containing compounds.