147589-78-4

Upstream product

• 147589-61-5 (2S,3Z)-6-(tert-butyloxy)-3-hexen-1,2-diol 
• 147589-63-7 (2S,3Z)-6-(tert-butyloxy)-1,2-epoxy-3-hexene 
• 147589-75-1 (2Z,5R,6Z)-9-(tert-butyloxy)-2,6-nonadien-1,5-diol 
• 147589-62-6 Toluene-4-sulfonic acid (Z)-(S)-6-tert-butoxy-2-hydroxy-hex-3-enyl ester 
• 147589-64-8 (5R,6Z)-9-(tert-butyloxy)-1-(tetrahydropyran-2-yloxy)-nona-6-en-2-yne-5-ol 
• 147589-76-2 (2Z,5R,6Z)-9-(tert-butyloxy)-1-triphenylmethyloxy-2,6-nonadien-5-ol 

Relevant academic research and scientific papers

Acyclic diastereocontrol and asymmetric transmission via anionic oxy-Cope rearrangement. Synthesis of key precursors of (+)-faranal and (-)-antirhine

The anionic oxy-Cope rearrangements of acyclic 1,5-dien-3-ols, when their stereochemistries are properly designated, are shown to proceed with a high level of diastereoselection and asymmetric transmission. The utility of the acyclic oxy-Cope variants is