147593-90-6Relevant articles and documents
Formamide Catalysis Facilitates the Transformation of Aldehydes into Geminal Dichlorides
Huy, Peter Helmut
supporting information, p. 2474 - 2483 (2019/06/08)
Herein, a novel method for the transformation of aldehydes into geminal dichlorides based on phthaloyl chloride as reagent and N -formylpyrrolidine as Lewis base catalyst is disclosed. Given the mild reaction conditions, the current protocol is distinguished by high levels of functional group compatibility and scalability and is operationally simple. The in situ formation of a Vilsmeier Haack reagent type intermediate is likely to be essential for this organocatalytic nucleophilic substitution reaction.
Novel Compounds
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Page/Page column 38, (2011/06/24)
The present invention provides compounds of formula (I): wherein Ra, Rb, Rc, R1, R2, R3, X1, Y1, Z1, A, n and m are as defined in the specification, and pharmaceutically acceptable salts thereof, as well as processes for their preparation, pharmaceutical compositions containing them and their use in therapy.
Dendritic porphyrin-fullerene conjugates: Efficient light-harvesting and charge-transfer events
Schlundt, Sebastian,Kuzmanich, Gregory,Spaenig, Fabian,De Miguel Rojas, Gustavo,Kovacs, Christian,Garcia-Garibay, Miguel A.,Guldi, Dirk M.,Hirsch, Andreas
experimental part, p. 12223 - 12233 (2010/06/11)
A novel dendritic C60-H2P(ZnP)3 (P = porphyrin) conjugate gives rise to the successful mimicry of the primary events in photosynthesis, that is, light harvesting, unidirectional energy transfer, charge transfer, and charge