147598-21-8Relevant articles and documents
IMPROVEMENTS IN OR RELATING TO ORGANIC COMPOUNDS
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Paragraph 0106; 0108; 0109, (2016/11/24)
A process for the hydrogenation of a substrate comprising a carbon heteroatom double bond in the presence of a transition metal complex comprising a tridentate or bisdentate-ligand containing a nitrogen, sulphur and phosphorus atom, of which at least the N- and P- and optionally also the S-atom coordinates with the transition metal.
Accessible protocol for asymmetric hydroformylation of vinylarenes using formaldehyde
Morimoto, Tsumoru,Fujii, Tetsuji,Miyoshi, Kota,Makado, Gouki,Tanimoto, Hiroki,Nishiyama, Yasuhiro,Kakiuchi, Kiyomi
supporting information, p. 4632 - 4636 (2015/04/27)
We report herein on an accessible protocol for the asymmetric hydroformylation of vinylarenes using formaldehyde as a substitute for syngas. The regioselectivity (branched/linear = up to 96/4) and enantioselectivity (up to 95% ee) can be attributed to the use of chiral Ph-bpe as a ligand. This journal is