147609-12-9Relevant academic research and scientific papers
Synthesis of Fused Dihydro-1,2,4-thiadiazolimines from Cyano-substituted Azides and Acyl Isothiocyanates
L'abbe, Gerrit,Sannen, Ingrid,Dehaen, Wim
, p. 27 - 30 (2007/10/02)
Organic azides, bearing a nitrile function at the γ- or δ-position, react with acyl isothiocyanates to give fused dihydro-1,2,4-thiadiazolimines.Representative examples are given.In the case of 2-cyanobenzylazide and benzoyl isothiocyanate, the formation of 9b is accompanied by two side products, 15 and 16.Mechanisms are presented to explain the formation of the products.
