147622-34-2Relevant academic research and scientific papers
Polyfunctional phosphine ligands. Preparation of 4'-formyl-2-diphenylphosphinoacetophenone and its coordination properties
Soulivong, Daravong,Ziessel, Raymond,Matt, Dominique
, p. 207 - 216 (2007/10/02)
The trifunctional ligand C(O)CH2PPh2 (5) has been prepared in four steps (overall yield 50percent) starting from terephthalaldehyde mono-(diethylacetal) (1): reaction of 1 with CH3MgBr gives C6H4>CH(OH)CH3 (2).This is oxidize
Synthesis and coordination properties of novel polyfunctional phosphine ligands
Soulivong, Daravong,Matt, Dominique,Ziessel, Raymond,Douce, Laurent,Deschenaux, Robert
, p. 1151 - 1154 (2007/10/02)
4′-formyl-2-diphenylphosphino-acetophenone 5 has been prepared in four steps (50%) starting from terephtalaldehyde mono-(diethylacetal) 1. Condensation of 5 with the para-substituted anilines H2NA-i gives quantitatively the phosphine-imines 6-8
