147637-82-9Relevant academic research and scientific papers
Stereochemistry of Allylic Alkylation of the Tetracarbonyliron Complexes of (R)-1-Acetyl-5-isopropoxy-3-pyrrolin-2-one
Koot, Wim-Jan,Hiemstra, Henk,Speckamp, W. Nico
, p. 156 - 158 (1993)
The two diastereoisomeric title complexes react with allyltrimethylsilane in the presence of BF3*Et2O to give nucleophilic substitution at C-5 to the corresponding 5-allyl derivatives; the reaction of the cis-complex proceeds slowly and with predominant inversion, whereas trans-complex reacts quickly and with complete retention of configuration at C-5.
