1476769-36-4Relevant academic research and scientific papers
Palladacycle-catalyzed methylenecyclopropanation of bicyclic alkenes with propiolates
Mo, Dong-Liang,Yuan, Teng,Ding, Chang-Hua,Dai, Li-Xin,Hou, Xue-Long
, p. 11470 - 11476 (2013/12/04)
An efficient way to access functionalized methylenecyclopropanes has been developed by palladacycle-catalyzed cyclopropanation of bicyclic alkenes with propiolates in high yields. The structure of the palladacycle was kept intact in the reaction, shown by 31P NMR spectrum studies. A rational mechanism has been proposed with a deuterium-labeled experiment. The usefulness of the functionalized methylenecyclopropanes has also been demonstrated.
