147699-67-0

Usage

Explanation

The molecular formula represents the number of atoms of each element present in a molecule. In this case, the compound has 18 carbon (C), 10 hydrogen (H), 2 nitrogen (N), and 2 sulfur (S) atoms.
2. Nitrile compound

Explanation

A nitrile is a functional group with a carbon atom triple-bonded to a nitrogen atom (C≡N). 1,2-Benzenedicarbonitrile, 4,5-bis(phenylthio)- has two nitriles, indicating the presence of two C≡N groups.

Explanation

The compound contains two aromatic rings, which are planar, unsaturated ring structures with delocalized π electrons. These rings are typically made up of carbon atoms, and in this case, they are part of the benzene structure.

Explanation

The compound has two carbon-nitrogen bonds, which are part of the nitrile functional groups (C≡N).

Explanation

The compound contains two sulfur atoms, each bonded to a phenyl group.

Explanation

1,2-Benzenedicarbonitrile, 4,5-bis(phenylthio)is commonly used in organic synthesis, which is a subfield of chemistry focused on the formation and manipulation of carbon-containing compounds.
8. Industrial and research applications

Explanation

The compound can be found in various industrial and research applications, indicating its importance in the development and production of various products and materials.
9. Health and environmental risks

Explanation

It is important to handle 1,2-Benzenedicarbonitrile, 4,5-bis(phenylthio)- with caution, as it may pose health and environmental risks. This suggests that proper safety measures should be taken when working with this chemical, such as using personal protective equipment and following proper disposal procedures.

Aromatic rings

Two

Carbon-nitrogen bonds

Two

Sulfur atoms

Two

Phenylthio groups

Two
7. Organic synthesis

Upstream product

• 139152-08-2 4,5-dichlorophthalonitrile 
• 108-98-5 thiophenol 
• 206268-72-6 4-bromo-5-nitrophthalonitrile 
• 370067-36-0 5-nitro-4-(phenylthio)phthalodinitrile 
• 175883-98-4 4,5-diiodobenzene-1,2-dicarbonitrile 
• 649553-05-9 4-chloro-5-[4-(hydroxymethyl)phenoxy]phthalonitrile 
• 942-06-3 4,5-dichlorophthalic anhydride 
• 15997-89-4 4,5-dichlorophthalimide 
• 56962-08-4 4,5-dichlorophthalic acid 
• 147699-62-5 4,5-dichloro-1,2-benzenedicarboxamide 

Downstream Products

• 405066-91-3 5,6-bis(phenylthio)-1,3-diiminoisoindoline 

Relevant academic research and scientific papers

Nucleophilic substitution in 4-bromo-5-nitrophthalodinitrile: XV. Synthesis of bis-4,5-(phenylsulfanyl)phthalonitrile, octakis-4,5-(phenylsulfanyl)phthalocyanines, and their sulfo and alkylsulfamoyl derivatives

Novel water- and organic-soluble derivatives of octakis-4,5-(sulfanylphenyl)phthalocyanine and its magnesium and aluminum complexes were synthesized starting from 4,5-bis(phenylsulfanyl)phthalonitrile obtained by nucleophilic substitution of the bromine a

Aromatic Thioethers as Novel Luminophores with Aggregation-Induced Fluorescence and Phosphorescence

Here we report on a novel system based on aromatic thioethers with unique luminescence properties. Fifteen different compounds were investigated in detail on their luminescence properties using UV/Vis absorption and steady-state and time-resolved luminesc

Coordination and electrochemistry of new substituted manganese phthalocyanines

A number of substituted manganese phthalocyanines PcMn have been synthesized from the corresponding phthalonitriles with rather good yields (up to 67%) and high purity. All complexes were characterized by elemental analysis, electronic absorption spectra, and some of them by redox potentials. Three coordination forms - PcMn(II), PcMn(III)X and [LPcMn(III)]2O were fixed for all complexes. The equilibrium of three electronic isomers - Pc +· Mn(I) × L, PcMn(II) × Ln and Pc -· Mn(III) × 2L has been observed in solutions of all PcMn(II) in the presence of organic base L. Copyright

Electrochemical, spectroscopic and microscopic studies of new manganese phthalocyanine complexes in solution and as self-assembled monolayers on gold

Four new manganese(III) phthalocyanines (3a-d), octasubstituted at the peripheral position with pentylthio, decylthio, benzylthio, and phenylthio groups, respectively, were synthesized. Their specific electrochemical, spectroscopic and microscopic propert

Synthesis and antimycotic activity of new unsymmetrical substituted zinc phthalocyanines

The synthesis of new unsymmetrical substituted zinc phthalocyanines derivatives has been described; moreover the photodynamic activity of some compounds tested against Candida albicans has been reported.

Nucleophilic Substitution in 4-Bromo-5-nitrophthalodinitrile: VII. Synthesis and Properties of Phenylthio-substituted Phthalocyanine Metal Complexes

New phenylthio-substituted phthalodinitriles have been synthesized: 5-amino-4-phenylthio-, 5-acetylamino-4-phenylthio-, 5-octanoylamino-4- phenylthio-, 5-phenoxy-4-phenylthio-, 5-(4-carboxyphenoxy)-4-phenylthio-, 5-(4-tert-butylphenoxy)-4-phenylthio-, and 4,5-bis(phenylthio)phthalodinitriles. Their complexes with metals have been prepared and examined by spectral methods.

Effect of Peripheral Substitution on the Electronic Absorption and Fluorescence Spectra of Metal-Free and Zinc Phthalocyanines

The effect of substituents on the position and intensity of the electronic absorption and fluorescence spectra of phthalocyanines (Pcs) was examined for 35 Pc compounds. When electron-releasing groups are bound to four β-benzo positions of the Pc skeleton

Synthesis of soluble halogenated aryloxy substituted indium phthalocyanines

Phthalocyanines solubilised by either 8 or 16 aryloxy or haloaryloxy groups are described. A series of phthalocyanine derivatives were prepared containing indium. 1,2-Dinitriles and the corresponding diiminoisoindolines were used as precursors. A naphthalocyanine metallated with indium and solubilised with four tert-butyl groups is reported.

A simple synthesis of 4,5-disubstituted 1,2-dicyanobenzenes and 2,3,9,10,16,17,23,24-octasubstituted phthalocyanines

4,5-Dichloro-1,2-dicyanobenzene (5) was prepared in an overall yield of 49% from 4,5-dichloro-1,2-benzenedicarboxylic acid (1). The reactions of 5 with phenols, thiophenol and 1-propanethiol led in a nucleophilic displacement reaction to the 4,5-bis(aryloxy)-, 4,5-bis(phenylthio)- and 4,5-bis(propylthio)-1,2-dicyanobenzenes 6 which were converted in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene in high yields to octasubstituted phthalocyanines (tetrabenzoporphyrazines) 7. Some compounds 7 contain eight free phenolic, carboxylic acid or pyridyl groups.