14774-78-8

Basic information

• Product Name: Lithium,(4-chlorophenyl)-
• Synonyms: Lithium,(p-chlorophenyl)- (6CI,7CI,8CI); Benzene, chloro-, lithium complex; 4-Chlorophenyllithium; p-Chlorophenyllithium
• CAS NO: 14774-78-8
• Molecular Formula: C₆H₄Cl*Li
• Molecular Weight: 118.49
• Mol File: 14774-78-8.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Lithium,(4-chlorophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Lithium,(4-chlorophenyl)-(14774-78-8)
• EPA Substance Registry System: Lithium,(4-chlorophenyl)-(14774-78-8)

Safety Data

• Hazard Codes: 3:
• Safety Statements: −. See also LITHIUM COMPOUNDS." target="_blank">Explodes on contact with oxygen. When heated to decomposition it emits tox
• Hazardous Substances Data: 14774-78-8(Hazardous Substances Data)

Upstream product

• 106-39-8 bromochlorobenzene 
• 811-49-4 ethyllithium 
• 6944-25-8 tris(4-chlorophenyl)stilbane 
• 591-51-5 phenyllithium 
• 109-72-8 n-butyllithium 
• 637-87-6 1-Chloro-4-iodobenzene 
• 598-30-1 sec.-butyllithium 
• 15799-48-1 tetra(p-chlorophenyl)tin 
• 60-29-7 diethyl ether 

Downstream Products

• 411238-97-6 2-(4-chloro-phenyl)-7-methyl-quinoline 
• 50971-15-8 2-(4-chloro-phenyl)-6-methyl-quinoline 
• 874498-25-6 4,7-dichloro-2-(4-chlorophenyl)quinoline 
• 18678-60-9 meSi(ph-4-Cl)3 
• 18414-47-6 me2Si(ph-4-Cl)2 
• 99-91-2 para-chloroacetophenone 
• 88856-72-8 (4-chloro-phenyl)-triphenyl germane 
• 854891-24-0 2-(4-chlorophenyl)-6-methoxyquinoline 
• 80268-88-8 2-chloro-1-(4-chloro-phenyl)-1-phenyl-ethanol 
• 1423-73-0 4,4'-dichloro-α,α'-difluoro-stilbene 
• 32174-74-6 5-(4-chloro-phenyl)-5H-5λ³-dibenzoiodole 
• 19841-25-9 Penta-p-chlorphenyl-phosphoran 
• 22217-78-3 5-(4-chlorophenyl)-3,4-dihydro-2H-pyrrole 
• 89333-85-7 [1-(4-Chloro-phenyl)-allyl]-trimethyl-silane 

Relevant articles and documents

General and Mild Nickel-Catalyzed Cyanation of Aryl/Heteroaryl Chlorides with Zn(CN)2: Key Roles of DMAP

A new and general nickel-catalyzed cyanation of hetero(aryl) chlorides using less toxic Zn(CN)2 as the cyanide source has been developed. The reaction relies on the use of inexpensive NiCl2·6H2O/dppf/Zn as the catalytic system and DMAP as the additive, allowing the cyanation to occur under mild reaction conditions (50-80 °C) with wide functional group tolerance. DMAP was found to be crucial for successful transformation, and the reaction likely proceeds via a Ni(0)/Ni(II) catalysis based on mechanistic studies. The method was also successfully extended to aryl bromides and aryl iodides.

Relative basicities of ortho-, meta-, and para-substituted aryllithiums

(Chemical Equation Presented) The relative basicities of aryllithiums bearing methoxy, chlorine, fluorine, trifluoromethyl and trifluoromethoxy substituents at the ortho, meta, and para positions have been assessed. To this end, two aryllithiums of compar

Dopamine transporter imaging ligand

The 3α isomer of RTI-55, RTI-352, is an effective in vivo binding ligand that reflects greater selectivity for the dopamine transporter than is observed with RTI-55. In addition, there is also a more rapid achievement of apparent equilibrium in the striat