1477517-20-6

Basic information

• Product Name: C₂₆H₂₅OP
• CAS NO: 1477517-20-6
• Molecular Weight: 384.458
• Mol File: 1477517-20-6.mol

Chemical Properties

• Boiling Point: 530.1±50.0 °C(Predicted)
• CAS DataBase Reference: C₂₆H₂₅OP(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₆H₂₅OP(1477517-20-6)
• EPA Substance Registry System: C₂₆H₂₅OP(1477517-20-6)

Safety Data

• Hazardous Substances Data: 1477517-20-6(Hazardous Substances Data)

Upstream product

• 1477517-25-1 C₂₆H₂₅O₂P 
• 1477517-24-0 C₂₅H₂₃O₂P 
• 1338453-95-4 (S)-3-tert-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphol-4-yl trifluoromethanesulfonate oxide 
• 100622-34-2 anthracene-9-boronic acid 

Relevant articles and documents

Efficient syntheses of korupensamines A, B and michellamine B by asymmetric Suzuki-Miyaura coupling reactions

Efficient asymmetric Suzuki-Miyaura coupling reactions are employed for the first time in total syntheses of chiral biaryl natural products korupensamine A and B in combination with an effective diastereoselective hydrogenation, allowing ultimately a concise and stereoselective synthesis of michellamine B. Chiral monophosphorus ligands L1-3 are effective for the syntheses of a series of functionalized chiral biaryls by asymmetric Suzuki-Miyaura coupling reactions in excellent yields and enantioselectivities (up to 99% ee). The presence of a polar-π interaction between the highly polarized BOP group and the extended π system of arylboronic acid coupling partner is believed to be important for the high enantioselectivity.