14779-22-7Relevant academic research and scientific papers
Decomposition Reaction of 3-Aryl-6-disubstituted Amino-1,4,2,5-dithiadiazines in the Solid State
Yonemoto, Katsumi,Shibuya, Isao
, p. 2407 - 2409 (2007/10/02)
3-Diethylamino-6-phenyl-1,4,2,5-dithiadiazine, on standing in air at room temperature, decomposed to afford 5-diethylamino-3-phenyl- and 3,5-bis(diethylamino)-1,2,4-thiadiazoles, whereas in the melt and in solution it was remarkably stable.With increasing bulkiness of substituents (Ar and /or NR2) in 1,4,2,5-dithiadiazines, their stability in the solid state clearly enhanced.Some interstack interactions in the crystal seem to favor the decomposition.
STRUCTURE ELUCIDATION OF HECTOR'S BASE, DOST'S BASE, AND RELATED COMPOUNDS BY NITROGEN-15 and CARBON-13 N.m.r. SPECTROSCOPY
Butler, Anthony R.,Glidewell, Christopher,Hussain, Ishtiaq,Maw, Paul R.
, p. 1843 - 1863 (2007/10/02)
The structures, in solution, of Hector's Base, Dost's Base, and some related compounds have been deduced by considerations of their 15N and 13C n.m.r. spectra.
