147802-66-2Relevant academic research and scientific papers
D-secoestrone derivatives. V1:0 3-Methoxy-17-oxo-17-phenyl-16,17-secoestra-1,3,5(10)-triene-16-nitrile and 17-hydroxy-3-methoxy-17-phenyl-16,17-secoestra-1,3,5(10)-triene-16-nitrile
Lazar, Dusan,Stankovic, Slobodanka,Pejanovic, Vjera,Courseille, Christiane
, p. o63-o65 (2002)
The conformations of two secoestrone derivatives, C25H27NO2 and C25H29NO2 were determined. The compounds exhibited different conformations in the solid state, which was responsible for the
Photoinduced C—C Bond Cleavage and Oxidation of Cycloketoxime Esters
Zhao, Binlin,Tan, Hui,Chen, Cheng,Jiao, Ning,Shi, Zhuangzhi
supporting information, p. 995 - 999 (2018/09/25)
A novel structural reorganization of cycloketoxime esters beyond the traditional Beckmann rearrangement process has been established to build cyano-containing ketones in the presence of photocatalyst. This novel transformation is remarkable with selective C—C bond cleavage and an oxidation process enabled by DMSO used as the solvent, oxidant, and oxygen source avoiding acid, base and toxic cyanide salts as the cyano source. Further applications in late-stage modification of complex and chiral molecules have also been reported.
