147834-79-5Relevant articles and documents
Ortho-Selective Side-Chain Nitration of α-Bromoacylpolymethylbenzenes and its Application to the Syntheses of Indan-1-one and Inden-1-one Derivatives
Keumi, Takashi,Matsuura, Kazunori,Nakayama, Norihiro,Tsubota, Toshiaki,Morita, Toshio,et al.
, p. 537 - 556 (2007/10/02)
α-Bromoacylpolymethylbenzenes 2a - m react with fuming nitric acid in acetic anhydride to give 2-(nitromethyl)-(α-bromoacyl)polymethylbenzenes 3a - m in good isolated yields.Compounds 3a - j undergo the intramolecular nucleophilic substitution/cyclization