147838-45-7Relevant articles and documents
A Study of the Reactivity of Tricarbonyl(vinylketene)iron(0) Complexes Towards Alkynes
Morris, K. Gail,Saberi, Stephen P.,Salter, Matthew M.,Thomas, Susan E.,Ward, Mark F.,et al.
, p. 5617 - 5634 (1993)
Alkynes add to tricarbonyl(vinylketene)iron(0) complexes to generate stable 1:1 adducts, the structures of which were determined by an X-ray crystal structure analysis of the adduct formed from tricarbonyl(5-phenyl-3-iso-propyl-1-oxapenta-1,2,4-triene)iron(0) and dimethyl acetylenedicarboxylate.Addition of unsymmetrical alkynes is regioselective and the regiochemistries of the adducts isolated from these reactions were determined by X-ray crystal structure analyses of the products from but-3-yn-2-one and tricarbonyl(3-tert-butyl-5-phenyl-1-oxapenta-1,2,4-triene)iron(0), and of the structurally modified product derived from diethylpropynylamine and tricarbonyl(5-phenyl-3-iso-propyl-1-oxapenta-1,2,4-triene)iron(0).Thermolysis of the adducts leads to either cyclopentenediones or phenols and its outcome is dependent on the electronic properties of the carbon-1 substituent of the adduct.The phenols may be synthesised directly and regioselectively from tricarbonyl(vinylketene)iron(0) complexes and the appropriate alkynes.