147900-65-0Relevant academic research and scientific papers
The First Diazatetrathiafulvalenes
Chu, Suk-Ling,Wai, Kwok-Fai,Lai, Ting-Fong,Sammes, Michael P.
, p. 847 - 850 (1993)
Treatment of 1,4,2-dithiazolium salts, unsubstituted at C-5, with triethylamine yields mixed geometrical isomers of 5-(1,4,2-dithiazol-5-ylidene)-1,4,2-dithiazoles, in 10-28percent yields; X-ray analysis of the trans-3,3'-diphenyl derivative 5a shows the
Synthesis and Properties of Tetrathiadiazafulvalenes (R = H, Me, Ph)
Oakley, Richard T.,Richardson, John F.,Spence, Rupert E. v. H.
, p. 2997 - 3002 (1994)
Reduction of 5-(methylthio)-1,4,2-dithiazolium (3, R = H, Me, Ph) salts with zinc powder yields the corresponding diazahexathioorthooxalate derivatives (RCNS2)(MeS)CC(SMe)(S2NCR) (4, R = H, Me, Ph).Thermolysis of these materials in the presence of catalyt
Tetrathiadiazafulvalenes; Preparation and Characterisation of cis- and trans- (R = Me, Ph)
Oakley, Richard T.,Richardson, John F.,Spence, Rupert E. v. H.
, p. 1226 - 1227 (2007/10/02)
Tetrathiadiazafulvalenes can be prepared by the reductive coupling of 5-methylthio-1,4,2-dithiazolium salts, and thermolysis of the resulting hexathiooxalates; oxidation of tetrathiadiazafulvalenes affords the corresponding radical cations.
