147938-37-2Relevant academic research and scientific papers
PENTACOVALENT PHOSPHORUS IN ORGANIC SYNTHESIS: A NEW ROUTE TO SUBSTITUTED PHOSPHONATES
McClure, Cynthia K.,Jung, Kang-Yeoun,Grote, Christopher W.,Hansen, Karl
, p. 23 - 26 (2007/10/02)
The pentacovalent oxaphospholene derived from methyl vinyl ketone and trialkyl phosphite has been shown to condense with a variety of electrophiles to produce highly substituted phosphonates.
NOVL AND EFFICIENT SYNTHESIS OF URACIL PHOSPHONATE DERIVATIVES VIA PENTACOVALENT OXAPHOSPHOLENES
McClure, Cynthia K.,Grote, Christopher W.,Rheingold, Arnold L.
, p. 983 - 986 (2007/10/02)
2,2,2-Triethoxy-1,2λ5-oxaphospholene, 1, reacts under mild, neutral conditions with aryl isocyanates to produce the phosphonate-containing pyrimidinedione derivatives 2 and 3.X-ray structure determination of 3 confirmed its structure.Keywords:
