148020-10-4Relevant articles and documents
New Total Synthesis of (+)-N-Methylanisomycin by Anodic Cyclization of δ-Alkenylamine
Tokuda, Masao,Fujita, Hirotake,Miyamoto, Tohru,Suginome, Hiroshi
, p. 2413 - 2426 (2007/10/02)
A chiral total synthesis of (+)-N-methylanisomycin (1a) from L-diethyl tartrate via 15 steps is reported.The key step in the synthesis was a regio- and stereoselective cyclization of (E)-δ-alkenylamine 12a or its (Z)-isomer 12b by anodic oxidation of thei