148066-41-5Relevant academic research and scientific papers
Mechanochemical synthesis of cyclohexenones and indazoles as potential antimicrobial agents
Al-Bogami, Abdullah S.
, p. 5457 - 5477 (2016/06/01)
Abstract: Mechanical force from ball milling was used for efficient and quantitative preparation of a series of cyclohexenones and indazoles. The method is environmentally friendly, simple, short, and solventless. Unambiguous structural assignments of the
Synthesis, characterization of novel cyclohexenone derivatives and computation of their optical response
Badshah, Amir,Nazar, Muhammad Faizan,Mahmood, Asif,Ahmed, Waqas,Abdullah, Muhammad Imran,Zafar, Muhammad Naveed,Rana, Usman Ali
, p. 103 - 110 (2014/06/23)
The present study reports the successful development of five new cyclohexenone derivatives (CDs) using rational design synthesis principles and quantum chemical calculations. These new CDs were synthesized by following a convenient route of Robinson annulation, and the molecular structure of these CDs were later confirmed by various analytical techniques such as 1H NMR, 13C NMR, FT-IR, UV-Vis spectroscopy and Mass spectrometry. The results from spectroscopic studies show that the as-synthesized CDs molecules apparently emit violet light at about 406-414 nm. Moreover, polarizability (α) and first static hyperpolarizability (β) were computed by density functional theory (DFT). In addition, the UV-Vis spectra, transition character and electronic structures of these CDs were computed by using the time dependent density functional theory (TD-DFT). It was interesting to note that the values of computed and experimental electronic transitions (λmax) were in good agreement. Finally, the measurements of higher non-linear optical (NLO) response of our newly synthesized CDs suggest their potential for application in photonic devices.
Furylcyclohexenones. 1. Synthesis and properties of 3- and 5-furyl-6-ethoxycarbonylcyclohexenones
Usova,Lysenko,Krapivin,Kul'nevich
, p. 548 - 554 (2007/10/03)
3- and 5-Furylcyclohexenones were obtained by the Michael reaction of furan chalcones with acetoacetic ester. Intermediate β-cycloketols were isolated in many cases. It was found that transformations of β-cycloketols by HClO4 and TrClO4 were a function of the nature of the substituent in position 5 of the alicycle. 5-Arylketols undergo dehydration, while 5-furyl derivatives split both water and the furan fragment, resulting in aromatization of the alicycle. The structure of the synthesized compounds was confirmed by the IR and PMR spectra. 1996 Plenum Publishing Corporation.
