148089-62-7Relevant academic research and scientific papers
REACTIVITY OF VINYLTHIOHALOGENOBENZENES AND SYNTHESIS OF POLYFUNCTIONAL COMPOUNDS BASED ON THEM
Amosova, S. V.,Gostevskaya, V. I.,Gavrilova, G. M.,Afonin, A. V.,Toryashinova, D.-S. D.
, p. 2013 - 2018 (2007/10/02)
With azodiisobutyronitrile as initiator the products from full thiylation of the vinylthio groups in vinylthiohalogenobenzenes by propanethiol are formed.Nucleophilic substitution of the halogen atom by 2-aminoethanol in DMFA at 20-25 deg C in the presenc
REACTIONS OF SODIUM ETHENECHALCOGENOLATES WITH HEXAFLUOROBENZENE
Amosova, S. V.,Gostevskaya, V. I.,Gavrilova, G. M.,Afonin, A. V.,Romanenko, L. S.,Stefanik, L.
, p. 1154 - 1157 (2007/10/02)
The nucleophilic susbtitution of the fluorine atoms in hexafluorobenzene in reaction with sodium ethenethiolate and etheneselenolate, produced by the cleavage of divinyl sulfide and divinyl selenide with sodium in liquid ammonia, takes place at 20-30 deg C in DMFA with the formation of 1,2,4,5-tetrafluoro-3,6-bisbenzenes and 1,4-difluoro-2,3,5,6-tetrakis(vinylthio)benzene.The formation of the vinylthio-substituted fluorobenzenes and their yields probably depend on the basicity of the medium, the reagent ratio, and the order of mixing.
