148237-59-6

Upstream product

• 62761-90-4 α,α-bis(trimethylsilyl)methylphenyl sulfide 
• 37891-39-7 trimethylsilane 
• 124-13-0 Octanal 
• 108-98-5 thiophenol 
• 150098-08-1 1,1-bis(phenylthio)-1-nonene 
• 115993-80-1 1-Phenylthio-1-(trimethylsilyl)-1-nonene 

Relevant academic research and scientific papers

Electroinitiated Oxygenation of Alkenyl Sulfides and Alkynes in the Presence of Thiophenol

Electrolysis of alkenyl sulfides in the presence of thiophenol with bubbling of molecular oxygen gave the corresponding α-(phenylthio) carbonyl compounds with the consumption of a catalytic amount of electricity.An electroinitiated radical chain mechanism has been proposed.The reaction also took place without electrochemical initiation, but much (5-50 times) longer reaction time was required for the completion of the reaction.The potential utility of the present reaction in organic synthesis is demonstrated by the net 1,2-transposition of a phenylthio group and a carbonyl group.The electroinitiated oxygenation of ketene dithioacetals also proceeded smoothly to give the corresponding α-(phenylthio) thiol esters.It was also found that the electroinitiated oxygenation of alkynes in the presence of thiophenol gave α-(phenylthio) carbonyl compounds.A mechanism involving the initial formation of alkenyl sulfides has been proposed.

Electro-initiated oxygenation of alkenylsilanes in the presence of thiophenol

Electrolysis of alkenylsilanes in the presence of thiophenol with bubbling of molecular oxygen gave the corresponding α-phenylthio carbonyl compounds with the consumption of a catalytic amount of electricity. An electro-initiated radical chain mechanism i