1483-86-9Relevant academic research and scientific papers
Reaction of alkynyl(phenyl)(p-phenylene)bisiodonium ditriflates with nucleophiles. High reactivity of the alkynyl component
Kitamura, Tsugio,Fukuoka, Takahiro,Zheng, Lei,Fujimoto, Takeshi,Taniguchi, Hiroshi,Fujiwara, Yuzo
, p. 2649 - 2654 (1996)
Reaction of alkynyl (p-phenylene) bisiodonium ditriflates with potassium thiocyanate in DMF gave alkynyl thiocyanates and p-iodophenyl (phenyl) iodonium triflate. The latter was readily removed by washing with water. The exclusive sulfur attack of thiocya
A novel hypervalent iodine reagent prepared from o-iodosylbenzoic acid and trifluoromethanesulfonic acid preparation and reactions of alkynyl(o-carboxyphenyl)iodonium triflates
Kitamura, Tsugio,Nagata, Kensuke,Taniguchi, Hiroshi
, p. 1081 - 1084 (2007/10/02)
A hyervalent iodine reagent prepared from o-iodosylbenzoic acid and trifluoromethanesulfonic acid (TfOH) (1:2) showed a high reactivity toward aromatic substrates, giving aryl(o-carboxyphenyl)iodonium triflates in good to high yields. Treatment of the iodine reagent with 1-trimethylsilylalkynes afforded alkynyliodonium triflates bearing carboxy group in high yields. The alkynyliodonium triflates indicated a high efficiency as a Michael acceptor to nucleophiles and the o-carboxyphenyliodonio group behaved as a good leaving group.
