148332-31-4

Basic information

• Product Name: ETHYL 2,2':6',2''-TERPYRIDINE-4'-CARBOXYLATE
• Synonyms: [2,2':6',2''-TERPYRIDINE]-4'-CARBOXYLIC ACID ETHYL ESTER;ETHYL 2,2':6',2''-TERPYRIDINE-4'-CARBOXYLATE;4'-Ethoxycarbonyl-2,2':6',2''-terpyridine
• CAS NO: 148332-31-4
• Molecular Formula: C₁₈H₁₅N₃O₂
• Molecular Weight: 305.33
• Mol File: 148332-31-4.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 492.9 °C at 760 mmHg
• Flash Point: 251.9 °C
• Appearance: /
• Density: 1.201 g/cm³
• CAS DataBase Reference: ETHYL 2,2':6',2''-TERPYRIDINE-4'-CARBOXYLATE(CAS DataBase Reference)
• NIST Chemistry Reference: ETHYL 2,2':6',2''-TERPYRIDINE-4'-CARBOXYLATE(148332-31-4)
• EPA Substance Registry System: ETHYL 2,2':6',2''-TERPYRIDINE-4'-CARBOXYLATE(148332-31-4)

Safety Data

• Hazardous Substances Data: 148332-31-4(Hazardous Substances Data)

Usage

General Description

ETHYL 2,2':6',2''-TERPYRIDINE-4'-CARBOXYLATE is a chemical compound with the molecular formula C20H16N4O2. It is a derivative of terpyridine, which is a tridentate ligand widely used in coordination chemistry and material science. ETHYL 2,2':6',2''-TERPYRIDINE-4'-CARBOXYLATE contains an ethyl ester group and a carboxylic acid group, making it useful for the synthesis of various coordination complexes and metal-organic frameworks. It has potential applications in catalysis, sensing, and molecular electronics due to its unique structure and coordination properties.ETHYL 2,2':6',2''-TERPYRIDINE-4'-CARBOXYLATE commonly used for its aromatic and custom-synthesized properties. It is important for creating compounds that have aromatic and biological structure.

Upstream product

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• 148332-36-9 [2,2′:6′,2′′-terpyridine]-4′-carboxylic acid 
• 1122-62-9 2-acetylpyridine 
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• 1286763-09-4 4’-ethoxycarbonyl-2,2’:6,2’‘-terpyridine N-oxide 
• 1570-45-2 isonicotinic acid ethylester 
• 924-44-7 glyoxylic acid ethyl ester 
• 90050-70-7 ethyl 2,6-dibromo-pyridine-4-carboxylate 

Relevant articles and documents

Ruthenium Complex-Incorporated Two-Dimensional Metal-Organic Frameworks for Cocatalyst-Free Photocatalytic Proton Reduction from Water

Ultrathin two-dimensional (2D) nanosheets with efficient light-driven proton reduction activity were obtained through the exfoliation of novel metal-organic frameworks (MOF), which were synthesized by using a bis(4′-carboxy-2,2′:6′,2″-terpyridine) ruthenium complex as a linker and 3d transition-metal (Mn, Co, Ni, and Zn) anions as nodes. The nanosheet of the Ni2+ node exhibits a photocatalytic hydrogen evolution rate of 923 ± 40 μmol g-1 h-1 at pH = 4.0, without the presence of any cocatalyst or cosensitizer. A combined experimental and theoretical study suggests a reductive quenched pathway for the photocatalytic hydrogen evolution by the nanosheet. The transition-metal nodes at the edge of the nanosheets are proposed as the active sites. Density functional theory (DFT) calculations attributed the different catalytic activities of the nanosheets to the discrepancy of H adsorption free energy at various transition-metal nodes.

Understanding the Excited State Behavior of Cyclometalated Bis(tridentate)ruthenium(II) Complexes: A Combined Experimental and Theoretical Study

The synthesis and characterization of the donor-acceptor substituted cyclometalated ruthenium(II) polypyridine complex isomers [Ru(dpb-NHCOMe)(tpy-COOEt)](PF6) 1(PF6) and [Ru(dpb-COOEt)(tpy-NHCOMe)](PF6) 2(PF6)

Covalent hybrids based on Re(i) tricarbonyl complexes and polypyridine-functionalized polyoxometalate: Synthesis, characterization and electronic properties

A series of [Re(CO)3Br(N^N)] (N^N = substituted 2,2′-bipyridine ligand) complexes based on polypyridine-functionalized Dawson polyoxometalate (1-3) has been synthesized. The new hybrids (4-6) were characterized by various analytical techniques, including absorption, vibrational and luminescence spectroscopies as well as electrochemistry. Both units, the polyoxometalate and the transition metal complex, retain their intrinsic properties. Their combination in the newly prepared hybrids results in improved photosensitization in the high-energy visible region. However, a complete quenching of the emission for the [Re(CO)3Br(N^N)] complexes is observed due to formation of a charge separated state, Re(ii)-POM-, as shown by quenching experiments as well as theoretical modelling via DFT.