148345-64-6

Basic information

• Product Name: 2-ETHOXY-1-NAPHTHALENEBORONIC ACID
• Synonyms: Boronic acid, (2-ethoxy-1-naphthalenyl)- (9CI);2-Ethoxynaphthalen-1-ylboronic acid;2-Ethoxy-1-naphthylboronic acid;2-Ethoxy-1-naphthalen-1-ylboronic acid
• CAS NO: 148345-64-6
• Molecular Formula: C₁₂H₁₃BO₃
• Molecular Weight: 216.04082
• Product Categories: ETHOXY;blocks;BoronicAcids;Aryl;Boronic Acids;Boronic Acids and Derivatives;Aryl Boronic Acids;Boronic Acids;Boronic Acids and Derivatives;Chemical Synthesis;Monosubstituted Aryl Boronic Acids;Organometallic Reagents
• Mol File: 148345-64-6.mol
• Article Data: 1

Chemical Properties

• Melting Point: 102-106 °C (dec.)(lit.)
• Boiling Point: 431.4°Cat760mmHg
• Flash Point: 214.7°C
• Appearance: /
• Density: 1.20
• Vapor Pressure: 3.29E-08mmHg at 25°C
• Refractive Index: 1.603
• CAS DataBase Reference: 2-ETHOXY-1-NAPHTHALENEBORONIC ACID(CAS DataBase Reference)
• NIST Chemistry Reference: 2-ETHOXY-1-NAPHTHALENEBORONIC ACID(148345-64-6)
• EPA Substance Registry System: 2-ETHOXY-1-NAPHTHALENEBORONIC ACID(148345-64-6)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 148345-64-6(Hazardous Substances Data)

Usage

Uses

Reactant for:? ;Pd-catalyzed Suzuki-Miyaura reaction1,2,3

InChI:InChI=1/C12H13BO3/c1-2-16-11-8-7-9-5-3-4-6-10(9)12(11)13(14)15/h3-8,14-15H,2H2,1H3

Upstream product

• 121-43-7 Trimethyl borate 
• 50389-70-3 1-bromo-2-ethoxynaphthalene 

Downstream Products

• 1157867-54-3 1-(2,6-dimethylphenyl)-2-ethoxynaphthalene 
• 1157867-55-4 2-ethoxy-1-(4-methoxy-2,6-dimethylphenyl)naphthalene 
• 78649-26-0 1-fluoro-2-ethoxynaphthalene 
• 1256544-75-8 10-(3-bromophenyl)benzo[b]naphtho[1,2-d]furan 
• 1256544-20-3 10-bromonaphthalene[2,1-b]benzofuran 
• 1256544-19-0 2-hydroxy-1-(2-fluoro-5-bromophenyl)naphthalene 
• 1256544-18-9 2-ethoxy-1-(2-fluoro-5-bromophenyl)naphthalene 
• 1335223-24-9 C₂₀H₁₆FNO 
• 1318764-34-9 3-(2-ethoxy-1-naphthyl)anthranilic acid 
• 1202273-94-6 3-[4-(2-ethoxynaphthalen-1-ylamino)phenyl]-3-hydroxy-2,2-dimethylpropionic acid methyl ester 
• 1079039-44-3 (3-(2-ethoxynaphthalen-1-yl)-2,6-dinitrophenyl)(phenyl)methanol 
• 1075748-95-6 C₁₈H₁₆N₂O₃ 
• 1075749-09-5 2-ethoxy-1-(2-methoxy-5-nitrophenyl)naphthalene 

Relevant articles and documents

Palladium-Catalyzed Enantioselective Synthesis of 2-Aryl Cyclohex-2-enone Atropisomers: Platform Molecules for the Divergent Synthesis of Axially Chiral Biaryl Compounds

The palladium-catalyzed asymmetric synthesis of enone-based atropisomers from 2-iodo-3-methylcyclohex-2-enones and aryl boronic acid is reported. BoPhoz-type phosphine–aminophosphine ligands showed superior enantioselectivity over other ligands. These cyc