148345-92-0Relevant academic research and scientific papers
NMR studies of proton transfer in 1:1 Tris(trimethoxyphenyl)-phosphine oxide-phenol complexes
Lagier, Claudia M.,Olivieri, Alejandro C.,Harris, Robin K.
, p. 1791 - 1796 (1998)
The hydrogen transfer process in adducts between tris(trimethoxyphenyl)phosphine oxide (TMPPO) and eight different substituted phenols has been studied in both the solution and solid states. For this purpose, 1H and 31P NMR solution-
The Trityl-Cation Mediated Phosphine Oxides Reduction
Landais, Yannick,Laye, Claire,Lusseau, Jonathan,Robert, Frédéric
supporting information, p. 3035 - 3043 (2021/05/10)
Reduction of phosphine oxides into the corresponding phosphines using PhSiH3 as a reducing agent and Ph3C+[B(C6F5)4]? as an initiator is described. The process is highly efficient, reducing a broad range of secondary and tertiary alkyl and arylphosphines, bearing various functional groups in generally good yields. The reaction is believed to proceed through the generation of a silyl cation, which reaction with the phosphine oxide provides a phosphonium salt, further reduced by the silane to afford the desired phosphine along with siloxanes. (Figure presented.).
Catalytic asymmetric cyano-ethoxycarbonylation reaction of aldehydes using a YLi3tris(binaphthoxide) (YLB) complex: Mechanism and roles of achiral additives
Yamagiwa, Noriyuki,Tian, Jun,Matsunaga, Shigeki,Shibasaki, Masakatsu
, p. 3413 - 3422 (2007/10/03)
Full details of a catalytic asymmetric cyano-ethoxycarbonylation reaction promoted by a heterobimetallic YLi3tris(binaphthoxide) complex (YLB 1), especially mechanistic studies, are described. In the cyanation reaction of aldehydes with ethyl c
