148705-98-0

Basic information

• Product Name: Cyclohexaneacetonitrile, a-[[(4-methylphenyl)sulfonyl]oxy]-, (R)-
• CAS NO: 148705-98-0
• Molecular Formula: C15H19NO3S
• Molecular Weight: 293.387
• Mol File: 148705-98-0.mol

Chemical Properties

• CAS DataBase Reference: Cyclohexaneacetonitrile, a-[[(4-methylphenyl)sulfonyl]oxy]-, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexaneacetonitrile, a-[[(4-methylphenyl)sulfonyl]oxy]-, (R)-(148705-98-0)
• EPA Substance Registry System: Cyclohexaneacetonitrile, a-[[(4-methylphenyl)sulfonyl]oxy]-, (R)-(148705-98-0)

Safety Data

• Hazardous Substances Data: 148705-98-0(Hazardous Substances Data)

Upstream product

• 4354-47-6 (R)-2-cyclohexyl-2-hydroxyacetonitrile 
• 98-59-9 p-toluenesulfonyl chloride 
• 74-90-8 hydrogen cyanide 
• 2043-61-0 cyclohexanecarbaldehyde 

Downstream Products

• 781592-33-4 (S)-Amino-cyclohexyl-acetonitrile 
• 240435-47-6 thioacetic acid S-(cyano-cyclohexyl-methyl) ester 
• 240435-60-3 (S)-Benzylsulfanyl-cyclohexyl-acetonitrile 
• 175790-74-6 (S)-Azido-cyclohexyl-acetonitrile 
• 125043-47-2 2-(S)-cyclohexylaziridine 

Relevant articles and documents

A convenient preparation of 2-substituted (S)-aziridines

2-Monosubstituted (S)-aziridines (S)-3 were obtained by hydrogenation of (R)-2-sulfonyloxynitriles (R)-2 with LiAlH4 in good chemical yields and high enantiomeric excess.

Enzyme-Catalyzed Reactions, 15. - Preparation of (R)-2-(Sulfonyloxy)nitriles and their Reactions with Acetates - Inversion of the Configuration of Optically Active Cyanohydrins

2-(Sulfonyloxy)nitriles (R)-6,7,8 are obtained in high optical purity from the respective cyanohydrins (R)-2 by sulfonylation with methanesulfonyl chloride (3), toluenesulfonyl chloride (4), and trifluoromethanesulfonic anhydride (5), respectively.In cont