14874-82-9 Usage
Reaction
Precatalyst for hydroformylation of olefins.
Precatalyst for silylformylation of olefins.
Precatalyst for carbonylative silylcarbo-cyclization in the syntheses of isodomoic acids.
Precatalyst for the conjugate addition of aryl- and alkenylboronic acids to enones.
Chemical Properties
Red/Green Crystalline Powder
Uses
Different sources of media describe the Uses of 14874-82-9 differently. You can refer to the following data:
1. (Acetylacetonato)dicarbonylrhodium(I) is used in in situ formation of a floors-soluble hydroformylation catalyst of interest in molecular engineering. It is also used as a catalyst for various carbonylation reactions, silylcarbocyclizations, conjugate additions to eons, carbamoylstannation, and reduction of aromatic nitro compounds. It is also used in Hydroformylation reaction.
2. Employed in in situ formation of a fluorous-soluble hydroformylation catalyst of interest in molecular engineering.
3. Umicore Precatalysts for Asymmetric and Cross-Coupling CatalysisCatalyst for various carbonylation reactions, silylcarbocyclizations,conjugate additions to enones, carbamoylstannation,and reduction of aromatic nitro compounds
Flammability and Explosibility
Flammable
Check Digit Verification of cas no
The CAS Registry Mumber 14874-82-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,8,7 and 4 respectively; the second part has 2 digits, 8 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 14874-82:
(7*1)+(6*4)+(5*8)+(4*7)+(3*4)+(2*8)+(1*2)=129
129 % 10 = 9
So 14874-82-9 is a valid CAS Registry Number.
InChI:InChI=1/C5H8O2.2CO.Rh/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;;;/q;;;+1/p-1/b4-3-;;;/rC5H7O2Rh.2CO/c1-4-3-5(2)7-8-6-4;2*1-2/h3H,1-2H3;;
