1488154-50-2Relevant academic research and scientific papers
Isocyanide and phosphine oxide coordination in binuclear chromium Pacman complexes
Stevens, Charlotte J.,Nichol, Gary S.,Arnold, Polly L.,Love, Jason B.
, p. 6879 - 6882 (2013)
The new binuclear chromium Pacman complex [Cr2(L)] of the Schiff base pyrrole macrocycle H4L has been synthesized and structurally characterized. Addition of isocyanide, CiNR (R = xylyl, tBu), or triphenylphosphine oxide donors to [Cr2(L)] gives contrasting chemistry with the formation of the new coordination compounds [Cr 2(μ-CNR)(L)], in which the isocyanides bridge the two Cr(II) centers, and [Cr2(OPPh3)2(L)], a Cr(II) phosphine oxide adduct with the ligands exogenous to the cleft.
