148839-62-7

Basic information

• Product Name: (4S,6S)-4-Benzyloxymethyl-2,2,6-trimethyl-[1,3]dioxan-5-one
• Synonyms: (4S,6S)-4-Benzyloxymethyl-2,2,6-trimethyl-[1,3]dioxan-5-one
• CAS NO: 148839-62-7
• Molecular Weight: 264.321
• Mol File: 148839-62-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (4S,6S)-4-Benzyloxymethyl-2,2,6-trimethyl-[1,3]dioxan-5-one(CAS DataBase Reference)
• NIST Chemistry Reference: (4S,6S)-4-Benzyloxymethyl-2,2,6-trimethyl-[1,3]dioxan-5-one(148839-62-7)
• EPA Substance Registry System: (4S,6S)-4-Benzyloxymethyl-2,2,6-trimethyl-[1,3]dioxan-5-one(148839-62-7)

Safety Data

• Hazardous Substances Data: 148839-62-7(Hazardous Substances Data)

Upstream product

• 148839-54-7 [(4R,6S)-4-Benzyloxymethyl-2,2,6-trimethyl-[1,3]dioxan-(5Z)-ylidene]-((S)-2-methoxymethyl-pyrrolidin-1-yl)-amine 
• 3587-60-8 Benzyloxymethyl chloride 
• 126178-07-2 (S)-(+)-1-(2,2-dimethyl-1,3-dioxan-5-ylidenamino)-2-methoxymethylpyrrolidine 
• 74-88-4 methyl iodide 
• 53104-32-8 (5-amino-2,2-dimethyl-1,3-dioxan-5-yl)methanol 
• 74181-34-3 2,2,-dimethyl-1,3-dioxan-5-one 
• 126177-98-8 ((S)-2-Methoxymethyl-pyrrolidin-1-yl)-[(S)-2,2,4-trimethyl-[1,3]dioxan-(5E)-ylidene]-amine 

Downstream Products

• 148839-55-8 (2S,4S)-1-Benzyloxy-2,4-dihydroxy-pentan-3-one 
• 148839-56-9 (4S,5R,6S)-4-Benzyloxymethyl-2,2,6-trimethyl-[1,3]dioxan-5-ol 

Relevant articles and documents

Preparation and reactions of 2,2-dimethyl-1,3-dioxan-5-one-SAMP-hydrazone: A versatile chiral dihydroxyacetone equivalent

The SAMP-hydrazone of 2,2-dimethyl-1,3-dioxan-5-one represents a valuable chiral dihydroxyacetone equivalent. Asymmetric mono- or α,α′-bisalkylations followed by auxiliary cleavage leads to the corresponding mono- or α,α′-disubstituted, acetonide protected ketodiols in excellent diastereo- and enantiomeric excesses.