149111-11-5Relevant academic research and scientific papers
Evidence of hydrogen migration in an alkylphenyldiazirine excited state
Zhang, Yunlong,Kubicki, Jacek,Platz, Matthew S.
, p. 3182 - 3184 (2010)
(Figure Presented) Ultrafast photolysis (350 nm) of alkylphenyldiazirines promotes the diazirine to the S1 excited state. Solvent and substituent effects on the excited state lifetimes indicate that the S 1 state is highly polarized and undergoes a [1,2]-H shift in concert with nitrogen extrusion in cyclohexane.
