14912-34-6Relevant academic research and scientific papers
Intramolecular Hydrogen Abstraction. (Diacetoxyiodo)benzene, a Useful Reagent for the Remote Functionalization of Non-Activated Carbon Atoms
Dorta, Rosa L.,Francisco, Cosme G.,Hernandez, Rosendo,Salazar, Jose A.,Suarez, Ernesto
, p. 1836 - 1854 (2007/10/02)
Photolysis with visible light of several hydroxy compounds such as (-)-6,6-dimethylbicycloheptan-2β-ol (1), 2-ethoxycarbonylmethyl-6,6-dimethylbicycloheptan-2β-ol (2), cedrol (5), isolongifolol (8), the hydrindane derivative (12), labdane-8α,15-diol (18), methyl 8α-hydroxylabdan-15-oate (19), labdanolic acid (20), methyl 3β-hydroxyfriedelan-29-oate (27), and friedelane-3β,30-diol 30-acetate (30) in the presence of (diacetoxyiodo)benzene and iodine leads to alkoxyl radicals which undergo intramolecular abstraction of suitably positioned hydrogen atoms to produce γ-functionalized derivatives.
