149209-41-6Relevant academic research and scientific papers
Siliciumverbindungen mit starken intramolekularen sterischen Wechselwirkungen XLIX. Disilane und ein Disilen mit unsymmetrischer Substitution an den Siliciumatomen
Weidenbruch, Manfred,Pellmann, Andrea,Pan, Youlin,Pohl, Siegfried,Saak, Wolfgang,Marsmann, Heinrich
, p. 67 - 71 (2007/10/02)
Treatment of chlorobis(2,4,6-triisopropylphenyl)silane (Ar2SiHCl) with lithium naphthalenide and subsequent addition of the chlorosilanes R2SiHCl (R = iPr, tBu, Mes) gives the unsymmetrical disilanes R2HSiSiHAr2 which are smoothly co
Linear 2,2-diaryl-substituted trisilanes: structure and photolysis to disilenes
Archibald, R. Scott,Winkel, Yvar van den,Powell, Douglas R.,West, Robert
, p. 67 - 72 (2007/10/02)
Synthesis of the new disilene, E/Z-IsMesSi=SiIsMes (1) is reported; the isomer Is2Si=SiMes2 (2) was obtained by photolysis of a mixture of Mes2Si(SiMe3)2 (3) and Is2Si(SiMe3)2 (5).Isomerization of 1 2 does not take place up to 80 deg C.X-Ray crystal s
