14931-91-0Relevant academic research and scientific papers
Reduction of fluoropentaamminecobalt(III) by 1-ethoxyethyl and 2-hydroxy-2-propyl radicals: A kinetic competition study
Mchatton, Ron C.,Espenson, James H.
, p. 784 - 786 (2008/10/08)
Kinetic competition experiments on the indicated reactions were conducted at 25°C and μ = 1.00 M. The rate constants are as follows: ·C(CH3)2OH, 2.2 × 106 M-1 s-1; ·CH(CH3)OC2H5, 1.1 × 106 M-1 s-1. The independently known rate constants for the competing reagents (Co(en)33+ and Co(NH3)5Cl2+, respectively) were used in the evaluation of the results.
