14934-02-2

Basic information

• Product Name: N-(4-chlorophenyl)benzenesulfinamide
• Synonyms: benzenesulfinamide, N-(4-chlorophenyl)-; N-(4-Chlorophenyl)benzenesulfinamide
• CAS NO: 14934-02-2
• Molecular Formula: C₁₂H₁₀ClNOS
• Molecular Weight: 251.7319
• Mol File: 14934-02-2.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 406.5°C at 760 mmHg
• Flash Point: 199.6°C
• Density: 1.39g/cm³
• Vapor Pressure: 8.13E-07mmHg at 25°C
• Refractive Index: 1.691
• CAS DataBase Reference: N-(4-chlorophenyl)benzenesulfinamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-chlorophenyl)benzenesulfinamide(14934-02-2)
• EPA Substance Registry System: N-(4-chlorophenyl)benzenesulfinamide(14934-02-2)

Safety Data

• Hazardous Substances Data: 14934-02-2(Hazardous Substances Data)

Upstream product

• 618-41-7 Benzenesulfinic acid 
• 108-98-5 thiophenol 
• 4972-29-6 benzenesulphinyl chloride 
• 106-47-8 4-chloro-aniline 
• 14933-95-0 N-(4-chlorophenyl)benzenesulfenamide 

Downstream Products

• 56158-15-7 (±)-((4-chlorophenyl)imino)(methyl)(phenyl)-λ⁶-sulfanone 
• 83706-28-9 N-(4-Chlorophenyl)benzenesulfonimidoyl Fluoride 

Relevant articles and documents

LDA-promoted decomposition of benzenesulfenamides. A route to aminyl radicals by dioxygen oxidation of lithium amides

The LDA-promoted decomposition of N-monosubstituted sulfenamides 1a-d occurs through the formation of thioaminyl anions, which undergo oxidation either at sulfur, with formation of sulfonamides, or at nitrogen, with formation of thioaminyl radicals, depending on the nature of the 4'-substituent. The reaction of N,N-disubstituted sulfenamides 1e-h proceeds through the intermediacy of a lithium complex capable of generating aminyl radicals via sulfenyl group transfer to the di-iso-propylamido anion and subsequent aerial oxidation of the resulting lithium amides 3e-h.