1493774-01-8Relevant academic research and scientific papers
Syntheses, crystal structures, and properties of a Salamo-type Tetradentate Chelating Ligand and its Pentacoordinated Copper(II) complex
Dong, Wen-Kui,Wang, Zheng-Kun,Li, Gang,Zhao, Meng-Meng,Dong, Xiu-Yan,Liu, Sen-Hua
, p. 2263 - 2268 (2013)
A Salamo-type ligand 6,6'-diethoxy-2,2'-[1,1'-(ethylenedioxydinitrilo) dimethylidyne]diphenol (H2L) and its pentacoordinate copper(II) complex [CuL(H2O)] were synthesized and structurally characterized. The molecule of H2L is located in a crystallographic inversion center and adopts E configuration with respect to the C=N bond. In the complex [CuL(H2O)], the CuII atom has a tetragonally elongated square-pyramidal configuration with donor atoms N2O2 forming a perfect basal plane. And an infinite 2D layer supramolecular structure is formed through intermolecular C1-H1AO5 and C2- H 2AO3 hydrogen bonding interactions.
