149431-65-2Relevant academic research and scientific papers
REACTIONS OF 1,1-DIALKYLTHIOSEMICARBAZIDES WITH PROPIOLIC ACID AND ITS ESTERS
Kauss, V. Ya.,Mishnev, A. F.,Kalvin'sh, I. Ya.
, p. 1439 - 1444 (1992)
The betaines 2-amino-4,4-dimethyl-Δ2-1,3,4-thiadiazolin-4-io-5-acetates are formed in the reaction of 1,1-dimethylthiosemicarbazides with propiolic acid. 2-Amino-4,4-disubstituted-5-carboalkoxy-methyl-Δ2-1,3,4-thiadiazolinium chlorides, the structure of which has been confirmed by X-ray crystallography, are formed by the reaction of 1,1-disubstituted thiosemicarbazides lower alkyl propiolates in the presence of hydrochloric acid.
