149439-07-6Relevant articles and documents
Synthesis and spectroscopic studies of di-s- and t-butyltin(IV) carboxylates
Jain, Vimal K.,Mokal, Vijaya B.
, p. 861 - 864 (2007/10/02)
Di-s- and t-butyltin(IV) carboxylates, xSn(OOCAr)2> (x = sec. or tert.; Ar = C6H5, C6H4OMe-2, 2-C4H3O, 2-C4H3S, 2-C5H4N, 2-C9H6N and 2-C4H3N2) have been prepared and characterized.Carboxylate moiety acts in a bidentate fashion either by coordination through both the oxygen atoms in an asymmetrical manner or chelating through nitrogen in case of ligands containing nitrogen heterocycles.Spectroscopic data (IR and NMR) suggest that these compounds adopt a six-coordinate configuration in solution.