149442-25-1Relevant academic research and scientific papers
A New Synthetic Route to β-Hydroxythioethers from Carbonyl Compounds Using Samarium(II) Diiodide (SmI2)
Yamashita, Masayuki,Kitagawa, Kazuhiro,Ohhara, Takashi,Iida, Yoshiko,Masumi, Akiko,et al.
, p. 653 - 656 (2007/10/02)
In the presence of samarium diiodide (SmI2) in THF, chloromethyl sulfides reacted with carbonyl compounds to give β-hydroxythioethers under mild and neutral conditions in moderate to good yields.
O-SILYLATED ENOLATE PHENYLTHIOALKYLATION: a SYNTHESIS OF α,β-UNSATURATED 5- AND 6-MEMBERED LACTONES.
Khan, Hassan A.,Paterson, Ian
, p. 5083 - 5084 (2007/10/02)
ZnBr2-catalysed phenylthioalkylation of keten bis(trimethylsilyl)acetals, obtained from carboxylic acids, with appropriate α-chlorosulphides can be used to prepare γ- and δ-lactones.
