1494739-77-3Relevant academic research and scientific papers
Electronic Delocalization in Two and Three Dimensions: Differential Aggregation in Indium “Metalloid” Clusters
Protchenko, Andrey V.,Urbano, Juan,Abdalla, Joseph A. B.,Campos, Jesús,Vidovic, Dragoslav,Schwarz, Andrew D.,Blake, Matthew P.,Mountford, Philip,Jones, Cameron,Aldridge, Simon
, p. 15098 - 15102 (2017)
Reduction of indium boryl precursors to give two- and three-dimensional M?M bonded networks is influenced by the choice of supporting ligand. While the unprecedented nanoscale cluster [In68(boryl)12]? (with an In12@In44@In12(boryl)12 concentric structure), can be isolated from the potassium reduction of a bis(boryl)indium(III) chloride precursor, analogous reduction of the corresponding (benzamidinate)InIIIBr(boryl) system gives a near-planar (and weakly aromatic) tetranuclear [In4(boryl)4]2? system.
