149478-12-6

Downstream Products

• 149512-70-9 {Pd(1,2-bis(dicyclohexylphosphino)ethane)(1,2-bis(diphenylphosphino)methane)} 
• 74525-11-4 {Pd(η1-1,1-bis(diphenylphosphino)methane)} 
• 31989-50-1 {Pd(1,2-bis(dimethylphosphino)ethane)2} 
• 364796-48-5 {Pd(η1-(1,2-bis(dimethylphosphino)ethane))n} 
• 149478-09-1 {Pd(1,2-bis(dicyclohexylphosphino)ethane)(1,2-bis(dimethylphosphino)ethane)} 

Relevant academic research and scientific papers

Acrylate formation from CO2 and ethylene: catalysis with palladium and mechanistic insight

We report the first catalyst based on palladium for the reaction of CO2, alkene and a base to form sodium acrylate and derivatives. A mechanism similar to a previously reported Ni(0)-catalyst is proposed based on stoichiometric in situ NMR experiments, isolated intermediates and a parent palladalactone. Our palladium catalyst was applied to the coupling of CO2 with conjugated alkenes.