149493-86-7Relevant academic research and scientific papers
Reactions of N,N-bis(silyloxy)enamines with sulfur-centered and sulfur-stabilised electrophiles
Ustinov, Aleksei V.,Dilman, Alexander D.,Ioffe, Sema L.,Strelenko, Yuri A.,Smit, William A.,Tartakovsky, Vladimir A.
, p. 74 - 76 (2007/10/03)
The coupling of N,N-bis(silyloxy)enamines with arylsulfenyl chlorides and episulfonium cations proceeds as an electrophilic attack at the β-carbon atoms of N,N-bis(silyloxy)enamines and affords functionalised aliphatic compounds.
Free radical addition reactions of allylic sulfones to alkenes
Harvey, Iain W.,Phillips, Eifion D.,Whitham, Gordon H.
, p. 6493 - 6508 (2007/10/03)
Intermolecular radical reactions involving formal addition of the sulfonyl and allyl fragments of an allylic sulfone across the double bond of an alkene are described. Reactions are most successful when the allylic sulfone has an electron withdrawing group at the 2-position. Only monosubstituted alkenes give useful yields of adducts, though both electron withdrawing and electron donating substituents are effective.
