14959-60-5Relevant academic research and scientific papers
Synthesis of (1H)-isochromen-1-imines by nickel-catalyzed reaction of 2-iodobenzamides with alkynes
Miura, Tomoya,Hiraga, Kentaro,Toyoshima, Takeharu,Yamauchi, Motoshi,Murakami, Masahiro
supporting information; experimental part, p. 798 - 800 (2012/09/07)
2-Iodobenzamides reacted with alkynes in the presence of a nickel(0)/P(4-ClC6H4)3 catalyst to produce substituted (1H)-isochromen-1-imines. The reaction proceeded through the formation of an oxanickelacycle, alkyne insertion, and reductive elimination.
