149625-80-9Relevant articles and documents
General Strategy for Stereoselective Synthesis of β- N-Glycosyl Sulfonamides via Palladium-Catalyzed Glycosylation
Dai, Yuanwei,Zheng, Jianfeng,Zhang, Qiang
, p. 3923 - 3927 (2018/07/21)
A highly efficient and mild glycosylation reaction between 3,4-O-carbonate glycal and N-tosyl functionalized aliphatic and aromatic amines via palladium-catalyzed decarboxylative allylation is disclosed. A wide range of highly functionalized 2,3-unsaturat
Total synthesis and proof of structure of a human breast tumor (globo-H) antigen
Park, Tae Kyo,Kim, In Jong,Hu, Shuanghua,Bilodeau, Mark T.,Randolph, John T.,Kwon, Ohyun,Danishefsky, Samuel J.
, p. 11488 - 11500 (2007/10/03)
The total synthesis of the Hakomori MBr1 antigen, heavily expressed on human breast tumors, is related. The construction involved the assembly of four glycals: (17 (twice), 18, 20, and 26) and an L-fucose derivative, 34. The sensitivity of the stereochemi