149676-04-0Relevant articles and documents
Fluorescence quenching of triarylamine functionalized phenanthroline-based probe for detection of picric acid
Parvathy,Dheepika,Abhijnakrishna,Imran,Nagarajan
, (2020)
Detection of toxic nitro aromatic compounds (NAC) using a cost-effective fluorescence sensing method have gained global attention. The current work demonstrates the selective sensing of picric acid using imidazo[4,5-f]-1,10-phenanthroline-triarylamines. T
Building Block Dependent Morphology Modulation of Cage Nanoparticles and Recognition of Nitroaromatics
Acharyya, Koushik,Chowdhury, Aniket,Mondal, Bijnaneswar,Chakraborty, Shubhadip,Mukherjee, Partha Sarathi
, p. 8482 - 8490 (2017)
Morphology of nanomaterials has a strong impact on their chemical/physical properties, and controlled synthesis of such materials with desirable morphology is a major challenge. This article presents the role of a building block in the morphology of organic cage particles. In this context, three organic cages (A3X2, B3X2, and C3X2) were devised from triphenylamine-based dialdehydes (A–C) and a flexible triamine (X) by utilizing dynamic imine chemistry. All of the synthesized cages were characterized by various spectroscopic techniques, which suggested the formation of [3+2] assembled architectures. Though the cages are isostructural, structural variation in the aldehyde building blocks imparted by the incorporation of phenyl moieties into the triphenylamine core produces morphologically diverse cage particles, as indicated by SEM. The synthesized cages were found to be fluorescent; the reduced analogue of cage A3X2 (A3X2r) was tested to explore its use as a chemosensor for the detection of nitroaromatic explosives. The experimental findings suggest high selectivity and sensitivity of A3X2r towards picric acid (PA) among the various nitroaromatics tested. A theoretical investigation of fluorescence quenching suggested that formation of a ground-state charge-transfer complex with a resonance energy-transfer (RET) process could be the main reason behind such selectivity of the cage towards PA.
Electrophilic aromatic substitution with diacyl imidazolium
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Page/Page column 24, (2010/02/17)
Polyimidazoline molecules and methods of making them are provided. A representative polyimidazoline has a structure: wherein: X is trifluoroacetyl or trifluoromethanesulfonyl; R1, R2, and R3 are each independently selected from a hydrogen, C1-C4 alkyl, C3-C7 cyclic alkyl, C1-C4 alkoxy, alcohol, and halogen; and n is 1 to 3.
Monoformylated arylamine processes and compounds
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Page/Page column 3; 6, (2010/11/26)
A process comprising for example reacting a substituted or unsubstituted arylamine or a mixture thereof with a Vilsmeier reagent in a solvent system comprising acetonitrile as a sole solvent or a solvent system comprising acetonitrile and one or more solv