149757-22-2Relevant academic research and scientific papers
Synthesis and properties of pentafluorosulfanyl group (Sf5)-containing meta-diamide insecticides
Issabayeva, Guldana,Kang, On-Yu,Kim, Jae Gon,Kim, Sang Mee,Lee, Won Hyung,Lee, Yaeji,Lim, Hwan Jung,Oh, In Seok,Park, Seong Jun
, (2020)
Herein, we describe novel pentafluorosulfanyl (SF5) group-containing meta-diamide insecticides. For the facile preparation of the SF5-based compounds 4a–d, practical synthetic methods were applied. Among newly synthesized compounds, 3-benzamido-N-(2,6-dimethyl-4-(pentafluoro-λ6-sulfanyl)phenyl)-2-fluorobenzamide 4d showed (i) a high insecticidal activity, (ii) an excellent selectivity to insects, and (iii) good levels of water solubility and log P values. In this study, we demonstrated that the pentafluorosulfanyl moiety could serve as an attractive functionality for the discovery of a new scope of crop-protecting agents.
Heterocyclic compounds and insecticidal use
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, (2008/06/13)
Compounds with insecticidal activity have the formula (I): STR1 wherein R1 is hydrogen, halogen, or a group NR4 R5 wherein R4 and R5 are independently selected from hydrogen or alkyl; R2 is a group --S(O)n R6 wherein n is 0, 1 or 2 and R6 is a haloalkyl group; R3 is --CN or is a group CX--NY1 Y2 for example --CS--NH2 ; and R7 and R8 , which may be the same or different, are halogen.
