149794-58-1Relevant academic research and scientific papers
Two methods for the synthesis of (2-mercaptophenyl)phosphonic acid
Masson,Saint-Clair,Saquet
, p. 485 - 486 (1993)
(2-Mercaptophenyl)phosphonic acid is prepared by hydrolysis of dialkyl (2-mercaptophenyl)phosphonate, which is itself formed either by reaction of dialkyl chlorophosphate with lithium 2-lithiobenzenethiolate, or from the lithiated derivative of the readily prepared O,O-diisopropyl S-phenyl thiophosphate whose phosphoryl group then undergoes an S → C migration.
Phosphorothioate-mercaptophosphonate rearrangement: Synthesis of new o-mercaptoaryl-and omercaptoheteroaryl phosphonates and their derivatives
Masson, Serge,Saint-Clair, Jean-Francois,Dore, Antonio,Saquet, Monique
, p. 951 - 964 (2007/10/03)
New o-mercaptoaryl and o-mcrcaptohetcroaryl phosphonates and their derivatives were prepared via an ori/io-lithiation of O,O-diisopropyl S-aryl, 5-(2-pyridyl), S-(2-thienyl) and 5-(3-thienyl) phosphorothioates followed by a phosphonyl group S → C migration. Elsevier,.
