149794-59-2

Upstream product

• 2574-25-6 Diisopropyl chlorophosphate 
• 108-98-5 thiophenol 
• 15267-38-6 thiophosphoric acid O,O'-diisopropyl ester S-phenyl ester 

Downstream Products

• 1446434-82-7 2-(4-cyanophenyl)-1,3-benzothiaphosphole 
• 1446434-81-6 2-(4-(trifluoromethyl)phenyl)-1,3-benzothiaphosphole 
• 1446434-80-5 2-(4-bromophenyl)-1,3-benzothiaphosphole 
• 1446434-79-2 2-(4-methoxyphenyl)-1,3-benzothiaphosphole 
• 76670-82-1 2-phenyl-1,3-benzothiaphosphole 
• 70048-90-7 1-mercapto-2-phosphinobenzene 
• 872359-28-9 diisopropyl 2-(chlorosulfinyl)phenylphosphonate 
• 872359-36-9 (diacetone-D-glucos-3-O-yl) 2-(diisopropoxyphosphoryl)benzenesulfenate 
• 872359-33-6 l-8-phenylmenthyl 2-(diisopropoxyphosphoryl)benzenesulfenate 
• 872359-37-0 1-(R)-(2,4,6-triisopropylphenyl)ethyl 2-(diisopropoxyphosphoryl)benzenesulfenate 

Relevant academic research and scientific papers

Phosphorothioate-mercaptophosphonate rearrangement: Synthesis of new o-mercaptoaryl-and omercaptoheteroaryl phosphonates and their derivatives

New o-mercaptoaryl and o-mcrcaptohetcroaryl phosphonates and their derivatives were prepared via an ori/io-lithiation of O,O-diisopropyl S-aryl, 5-(2-pyridyl), S-(2-thienyl) and 5-(3-thienyl) phosphorothioates followed by a phosphonyl group S → C migration. Elsevier,.

Two methods for the synthesis of (2-mercaptophenyl)phosphonic acid

(2-Mercaptophenyl)phosphonic acid is prepared by hydrolysis of dialkyl (2-mercaptophenyl)phosphonate, which is itself formed either by reaction of dialkyl chlorophosphate with lithium 2-lithiobenzenethiolate, or from the lithiated derivative of the readily prepared O,O-diisopropyl S-phenyl thiophosphate whose phosphoryl group then undergoes an S → C migration.